Sintesis Nanopartikel ZnO Menggunakan Prekursor ZnCl2 dan Polimer Penstabil Tween 80 Untuk Aplikasi Tabir Surya

Authors

  • Anisa Nurraeni Rozi Fakultas Matematika dan Ilmu Pengetahuan Alam, Universitas Advent Indonesia
  • Horasdia Saragih Fakultas Matematika dan Ilmu Pengetahuan Alam, Universitas Advent Indonesia

DOI:

https://doi.org/10.25077/jfu.14.6.585-594.2025

Keywords:

Nanoparticles synthesis, ZnO Nanoparticle, Sunscreen

Abstract

ZnO nanoparticles are semiconductor materials with a wide energy band gap (3.37 eV), making them excellent for use as sunscreen ingredients due to their superior ultraviolet protection properties. ZnO nanoparticles are superior to other conventional sunscreen materials because they do not cause skin irritation or allergies. The purpose of this study was to synthesize ZnO nanoparticles as a sunscreen material using Tween 80 stabilizing polymer and to comprehensively examine the effect of Tween 80 concentration on the characteristics of the resulting ZnO nanoparticle sunscreen. ZnO nanoparticles were synthesized using ZnCl2 and Tween 80 precursors with a Rotor Stator Homogenizer equipment system. Four different concentrations of Tween 80 were used to observe their effect on the characteristics of the resulting ZnO nanoparticles. The results showed that the average diameter of ZnO nanoparticles, their polydispersity index, and their zeta potential decreased as the concentration of Tween 80 used increased. Their optical transmittance was very high in the visible light spectrum and very low in the ultraviolet spectrum, especially for ZnO nanoparticles with the smallest average diameter (11.6 nm). This means that the visible light transmission and ultraviolet light absorption are excellent. In addition, the absorption edge is also very sharp. These three properties indicate that the ZnO nanoparticles produced are very suitable and have great potential for use as a sunscreen material.

References

Aldalbahi, A., Alterary, S., Almoghim, R. A., Awad, M. A., Aldosari, N. S., Alghannam, S. F., Alrashed, R. A. (2020). Greener Synthesis of Zinc Oxide Nanoparticles: Characterizaton and Multifaceted Applications. Molecules, 25(18), 4198. doi: https://doi.org/103390/moleculs25184198

Baskoutas, S. (2018). Special Issue: Zinc Oxide Nanostructures: Synthesis and Characterization. Materials, 11(6), 873. doi: https://doi.org/10.3390/ma11060873

Bhandari, K. P., Sapkota, D. R., Jamarkattel, M. K., Stillion, Q., & Collins, R. W. (2023). Zin Oxide Nanoparticles-Solution-Based Synthesis and Characterizations. Journal of Nanomaterials, 13(11), 1795. doi: https://doi.org/10.3390/nano13111795

Brus, L. E. (1983). A Simple Model for The Ionization Potential, Electron Affinity, and Aqueous Redox Potential of Small Seniconductor Crystallites. J. Chem, 5566-5571. doi: https://doi.org/10.1063/1.445676

Busila, M. (2018). ZnO Nanoparticles: Green Synthesis, Properties and Applications. Multimedia Systems, 41(3), 25-29. doi: https://doi.org/10.35219/MMS.2018.3.04

Chu, B., Biriukov, D., Bischoff, M., Predota, M., Sylvie, R., & Marchioro, A. (2023). Evolution of the electrical double layer with electrolyte concentration probed by second harmonic scattering. Royal Society of Chemistry, 246, 407-425. doi: https://doi.org/10.1039/D3FD00036B

Fan, B., Nan, F., Zhou, L., Lin, Y., & Liu, Y. (2025). Structural Transformation of ZnO Quantum Dots To ZnO/ZnS Core-Shell Quantum Dots and Fluorescence Color Shif From Yellow To Blue Induced By Intterfacial Sulfurization. Journal of Applied Physics, 137, 125101. doi: htts://doi.org/10.1063/50251672

Feng, Y., Kilker, S. R., & Lee, Y. (2020). Surface charge (zeta-potential) of nanoencapsulated food ingredients. In Characterization of Nanoencapsulaed food Ingredients, 213–241. doi: https://doi.org/10.1016/B978-0-12-815667-4.00007-9

Ginzburg, A. L., Blackburn, R. S., Santillan, C., Troung, L., Tanguay, R. L., & Hutchison, J. E. (2021). Zinc Oxide-Induced Changes to Sunscreen Ingredient Efficacy and Toxicity Under UV Irradiation. Photochem Photobiol Sci, 20(10), 1273-1285. doi:10.1007/s43630-021-00101-2

Gopmandal, P. P., & Duval, J. F. (2022). Electrostatics and Electrophoresis of Engineered Nanoparticles and Particulate Environmental Contaminants: Beyond Zeta Potential-Based formulation. Current Opinion in Colloid & Interface Science, 60, 10165. doi: https://doi.org/10.1016/j.cocis.2022.101605

Hussain, M.Z., Ru, K., Ali, R., & Khan, Y. (2014) Optical Properties of Laser Ablated ZnO Nanoparticles Prepared with Tween-80. Materials Letter, 122, 147-150. doi: https://doi.org/10.1016/J.MATLET.2014.02.022

Irede, E. L., Awoyemi, R. F., Owalabi, B., Aworinde, O. R., Kajola, R. O., Hazeez, A., Ifjen, I. H. (2024). Cutting-Edge Developments in Zinc Oxide Nanoparticles: Synthesis and Applicaions For Enhancd Antimicrobial and Healthcare Solutions. Royal Society Of Chemistry, 14, 20992-21034. doi:10.1039/D4RA02452D

Jain, A., & Bhise, K. (2022). A Review on Inorganic UV Filter Zinc Oxide Against Keratinocyte Cancer and Photoaging. International Journal of Advanced Chemistry Research, 4(2), 332-336. doi: 10.33545/26646781.2022.v4.i2e.119

Kiruthiga, A., Krishnakumar, T., & Kannan, R. (2019). The effect of surfactant on structural and optical properties of ZnO nanorods by wet chemical synthesis. AIP Conference Proceedings, 2142, 150017. doi: https://doi.org/10.1063/1.5122566

Klaseboer, E., & Chan, D. Y. (2020). On the deviation of the Smoluchowski result of electrophoretic mobility. Journal of Colloid and Interface Science, 568, 176-184. doi: https://doi.org/10.1016/j.jcis.220.02.032

Sahu, D., Panda, N. R., & Dash, D. (2020). ZnO Nanosheets Exhibiting High UV Blocking Efficiency for Effective Application in Sunscreen. Asian Journal of Chemistry, 32(7), 1809–1814. doi: https://doi.org/10.14233/AJCHEM.2020.22726

Singh, B., Singh, S., Singh, J., Saini, G. S., Mehta, D. S., Singh, G., Kaura, A. (2015). Understanding the adsorption behavior of surface active molecules on ZnO nanostructures by experimental and first-principles calculations. Physical Chemistry, 17(45), 30450-30460. doi: https://doi.org/10.1039/C5CP02949J

Sugiyana, D., Septiani, W., Mukyawan, A. S., & Wahyudi, T. (2018). Sintesis Nanopartikel ZnO dan Immobilisasinya Pada Kain Kapas Sebagai Absorber Ultraviolet. Arena tekstil, 32(2). doi:https://doi.org/10.31266/at.v32i2.3539

Xiong, S., George, S., Ji, Z., Lin, S., Yu, H., Damoiseaux, R., Loo, S. C. (2018). Size of TiO2 Nanoparticles Influences Their Phototoxicity: an In Vitro Investigation. Arc Toxicol, 87(1), 99-109. doi: https://doi.org/10107/s00204-012-0912-5

Zhao, S., Wang, Z., Wang, X., Kong, B., Liu, Q., Xia, X., & Liu, H. (2023). Characterization of Nanoemulsions Stabilized with Different Emulsifiers Efficiency for Oregano Essential Oil: Tween 80, Soybean Protein Isolate, Tea Saponin, and Soy Lecithin. Foods, 12(17), 3183. doi: https://doi.org/10.3390/foods12173183.

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Published

12-11-2025

How to Cite

Rozi, A. N., & Saragih, H. (2025). Sintesis Nanopartikel ZnO Menggunakan Prekursor ZnCl2 dan Polimer Penstabil Tween 80 Untuk Aplikasi Tabir Surya. Jurnal Fisika Unand, 14(6), 585–594. https://doi.org/10.25077/jfu.14.6.585-594.2025

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