Graphene-Based Electrode Materials via Liquid Phase Exfoliation from Chicken Feather Waste

Authors

  • Vamellia Sari Indah Negara Department of Mechanical Engineering, Politeknik Negeri Padang, 25163, Indonesia https://orcid.org/0009-0001-1711-195X
  • Sri Rahayu Alfitri Usna Department of Physics, Faculty of Mathematics and Natural Sciences, Universitas Andalas
  • Machmudah Machmudah Department of Physics, Faculty of Mathematics and Natural Sciences, Universitas Andalas
  • Astuti Astuti Department of Physics, Faculty of Mathematics and Natural Sciences, Universitas Andalas

DOI:

https://doi.org/10.25077/jfu.14.3.305-311.2025

Keywords:

Graphene, Liquid Phase Exfoliation, Chicken feather, Surfactant, Biomass Waste

Abstract

Graphene was successfully synthesized from chicken feather biomass waste using the Liquid Phase Exfoliation (LPE) method assisted by Linear Alkylbenzene Sulfonate (LAS) surfactant at varying volumes of 1 mL, 1.5 mL, and 2 mL. The aim of this study was to evaluate the potential of chicken feather-derived graphene as an electrode material for rechargeable batteries. Characterization using UV-Visible spectrophotometry showed a distinct absorption peak at approximately 270 nm, corresponding to the π→π* electronic transition, with increasing absorbance intensity observed with higher surfactant volumes, indicating more effective graphene exfoliation. XRD analysis revealed a shift in diffraction peaks to lower 2  angles, increased interlayer spacing (d-spacing), and the largest crystallite size of 13.58 nm at a surfactant volume of 1.5 mL. These results indicate that the surfactant plays a critical role in stabilizing and forming the crystalline structure of graphene. Overall, this study demonstrates that chicken feather-based graphene has promising potential to be developed as an eco-friendly electrode material in rechargeable battery applications

References

Al-Dhahebi, A. M., Gopinath, S. C. B., & Saheed, M. S. M. (2020). Graphene impregnated electrospun nanofiber sensing materials: a comprehensive overview on bridging laboratory set-up to industry. Nano Convergence, 7(1). https://doi.org/10.1186/s40580-020-00237-4

Edwards, R. S., & Coleman, K. S. (2013). Graphene synthesis: Relationship to applications. Nanoscale, 5(1), 38–51. https://doi.org/10.1039/c2nr32629a

Ferrari, A. C., Meyer, J. C., Scardaci, V., Casiraghi, C., Lazzeri, M., Mauri, F., Piscanec, S., Jiang, D., Novoselov, K. S., Roth, S., & Geim, A. K. (2006). Raman spectrum of graphene and graphene layers. Physical Review Letters, 97(18), 1–4. https://doi.org/10.1103/PhysRevLett.97.187401

Ghatule, M. P., & Devare, U. A. (2015). Study and Analysis on Synthesis of Graphene and its Applications in Solar Cells. International Journal of Innovative Research in Advanced Engineering, 2(1), 184–186. ijirae.com

Hernandez, Y., Nicolosi, V., Lotya, M., Blighe, F. M., Sun, Z., De, S., McGovern, I. T., Holland, B., Byrne, M., Gun’ko, Y. K., Boland, J. J., Niraj, P., Duesberg, G., Krishnamurthy, S., Goodhue, R., Hutchison, J., Scardaci, V., Ferrari, A. C., & Coleman, J. N. (2008). High-yield production of graphene by liquid-phase exfoliation of graphite. Nature Nanotechnology, 3(9), 563–568. https://doi.org/10.1038/nnano.2008.215

Hummers, W. S., & Offeman, R. E. (1958). Preparation of Graphitic Oxide. Journal of the American Chemical Society, 80(6), 1339. https://doi.org/10.1021/ja01539a017

Imawati, Y., Sukoharsono, E. G., & Wijaya, A. F. (2024). Toward the Future : Circular Economy Models for Sustainable Waste Management. 55(4).

Johra, F. T., Lee, J. W., & Jung, W. G. (2014). Facile and safe graphene preparation on solution based platform. Journal of Industrial and Engineering Chemistry, 20(5), 2883–2887. https://doi.org/10.1016/j.jiec.2013.11.022

K. S. Novoselov et al. (2016). Electric Field Effect in Atomically Thin Carbon Films. 306(5696), 666–669.

Kartick, B., Srivastava, S. K., & Srivastava, I. (2013). Green synthesis of graphene. Journal of Nanoscience and Nanotechnology, 13(6), 4320–4324. https://doi.org/10.1166/jnn.2013.7461

Li, G., Gao, B., Chu, P. K., & Huo, K. (2024). Biomass-derived graphene-like carbon materials for supercapacitor applications. 82–104. https://doi.org/10.1201/9781003387831-5

Parvez, K., Wu, Z. S., Li, R., Liu, X., Graf, R., Feng, X., & Müllen, K. (2014). Exfoliation of graphite into graphene in aqueous solutions of inorganic salts. Journal of the American Chemical Society, 136(16), 6083–6091. https://doi.org/10.1021/ja5017156

Taufantri, Y., Irdhawati, I., & Asih, I. A. R. A. (2016). Sintesis dan Karakterisasi Grafena dengan Metode Reduksi Grafit Oksida Menggunakan Pereduksi Zn. Jurnal Kimia VALENSI, 2(1), 17–23. https://doi.org/10.15408/jkv.v2i1.2233

Wang, Y., Li, Z., Wang, J., Li, J., & Lin, Y. (2020). Graphene and graphene oxide : biofunctionalization and applications in biotechnology. January. https://doi.org/10.1016/j.tibtech.2011.01.008

Zhang, L., & Zhao, X. S. (2009). Carbon-based materials as supercapacitor electrodes. Chemical Society Reviews, 38(9), 2520–2531. https://doi.org/10.1039/b813846j

Zhao, G., Wen, T., Chen, C., & Wang, X. (2012). Synthesis of graphene-based nanomaterials and their application in energy-related and environmental-related areas. RSC Advances, 2(25), 9286–9303. https://doi.org/10.1039/c2ra20990j

Zhao, X., Hayner, C. M., Kung, M. C., & Kung, H. H. (2011). Flexible Holey Graphene Paper Electrodes with Enhanced Rate Capability for Energy Storage Applications. 11, 8739–8749.

Zhu, Y., Murali, S., Cai, W., Li, X., Suk, J. W., Potts, J. R., & Ruoff, R. S. (2010). Graphene and graphene oxide: Synthesis, properties, and applications. Advanced Materials, 22(35), 3906–3924. https://doi.org/10.1002/adma.201001068

Downloads

Published

14-06-2025

How to Cite

Negara, V. S. I., Usna, S. R. A., Machmudah, M., & Astuti, A. (2025). Graphene-Based Electrode Materials via Liquid Phase Exfoliation from Chicken Feather Waste. Jurnal Fisika Unand, 14(3), 305–311. https://doi.org/10.25077/jfu.14.3.305-311.2025

Issue

Section

Articles