Karakterisasi Arus dan Tegangan Detektor Gas Hidrogen dari Bahan Semikonduktor Heterokontak TiO2/ZnO(Mg)
DOI:
https://doi.org/10.25077/jfu.12.2.213-219.2023Keywords:
Detektor, gas hidrogen, heterokontak, sensitivitas, waktu responAbstract
Telah dilakukan karakterisasi detektor gas hidrogen berupa pelet heterokontak. Pelet terdiri dari lapisan pertama TiO2 dan lapisan kedua ZnO didoping dengan 0%, 2%, 4%, 6%, 8%, dan 10% mol Mg. Pembuatan detektor diawali dengan pencampuran bahan, penggerusan bahan selama 4 jam, kalsinasi pada suhu 500 °C selama 4 jam, penggerusan ulang selama 1 jam, kompaksi menjadi pelet, dan sintering pada suhu 800 °C selama 4 jam menggunakan metode reaksi dalam keadaaan padat. Detektor gas diuji pada suhu ruang dengan karakterisasi I-V, penentuan nilai sensitivitas, selektivitas, konduktivitas, waktu respon, dan karakterisasi XRD. Pengukuran karakteristik I-V menunjukkan bahwa sampel TiO2/ZnO didoping 4% mol Mg memiliki sensitivitas tertinggi yaitu 6,33 dengan tegangan 21 volt pada suhu ruang. Nilai selektivitas tertinggi terdapat pada sampel TiO2/ZnO didoping 2% mol Mg yaitu 1,54 dengan teganan 30 volt. Konduktivitas tertinggi terdapat pada sampel TiO2/ZnO didoping 6% mol Mg sebesar 18,54/Ωm pada lingkungan hidrogen. Waktu respon sampel TiO2/ZnO didoping 4% mol Mg pada tegangan 21 volt adalah 42 s. Hasil XRD menunjukkan bahwa sampel ZnO yang didoping Mg memiliki ukuran kristal yang lebih kecil dibandingkan dengan sampel ZnO tanpa doping.References
Amelia, I. dan Elvaswer 2018, ‘Karakterisasi Arus-Tegangan Sensor Gas Hidrogen dari Bahan Semikonduktor SnO2 didoping dengan Na2CO3’, Jurnal Fisika Unand, vol. 7, no. 4, pp. 353-358.
Aygün, S., dan Cann, D. 2005, ‘ Hydrogen Sensitivity of doped CuO//ZnO heterocontact sensors’, Sensors and Actuators B, vol 106, no. 2, pp. 837-842.
Basthoh, E., Elvaswer, dan Harmadi 2013, ‘Karakterisasi ZnO Didoping TiO2 untuk Detektor LPG’, Jurnal ilmu Fisika (JIF), vol 5, no. 1, pp. 11-15.
Gu, H., Wang, Z., dan Hu, Y. 2012, ‘Hydrogen Gas Sensors Based on Semiconductor Oxide Nanostructures’, Sensors, vol. 12, pp. 5517-5550.
Hamdani, R. dan Elvaswer, 2018, ‘Karakterisasi Arus-Tegangan Sensor Gas Hidrogen dari Bahan Komposit Semikonduktor TiO2-SnO2’, Jurnal fisika Unand, vo. 7, no.1, pp. 73-79.
Ilnicka, A. dan Lukaszewicz, J.P. 2020, ‘Graphene-Based Hydrogen Gas Sensors: A review’, processes, vol. 8, no. 5.
KrÅ¡ko, O., Plecenik, T., MoÅ¡ko, M., Haidry, A.A., ÄŽurina, P.,Truchlý, M., GranÄiÄ, B., Gregor, M., Roch, T., Satrapinskyy, L., MoÅ¡ková, A., Mikula, M., Kúš, P., dan Plecenik, A. 2015, ‘Highly sensitive hydrogen semiconductor gas sensor operating at room temperature’, Proceedings of Eurosensors XXIX, Elsevier Procedia, Freiburg, 22.
Lai, T.Y., Fang, T.H., Hsiao, Y.J., dan Chan, C.A. 2019, ‘Characteristics of Au doped SnO2- ZnO heteronanostructures for gas sensing applications’, Vacuum, vol. 166, pp. 155-161.
Ren, Q., Cao, Y.Q., Arulraj, D., Liu, C., Wu, D., Li, W.M., Li, A.D. 2020, ‘Review-Resistive-Type Hydrogen Sensors Based on Zinc Oxide Nanostructures’, Journal of The Electrochemical Society,vol 167, no. 6.
Soundarrajan, P. dan Schweighardt, F., 2008, Hydrogen Fuel: Production, Transport, and Storage, CRS Press, Boca Raton.
Syafnur, Z. dan Elvaswer 2017, ‘Karakteristik Arus-Tegangan Semikonduktor Copper Oxide Didoping dengan Zinc Oxide Sebagai Sensor Gas Hidrogen’, Jurnal Fisika Unand, vol. 6, no. 2, pp. 176-182.
Tang, J., Zhang, X., Xiao, S., dan Zeng, F., 2017, Nanomaterials Based Gas Sensos for SF6 Decompositin Components Detection , IntechOpen, London.
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2023 Jurnal Fisika Unand
This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.
Please find the rights and licenses in JFU (Jurnal Fisika Unand).
1. License
The non-commercial use of the article will be governed by the Creative Commons Attribution license as currently displayed on Creative Commons Attribution-NonCommercial 4.0 International License.
2. Authors Warranties
The author warrants that the article is original, written by stated author(s), has not been published before, contains no unlawful statements, does not infringe the rights of others, is subject to copyright that is vested exclusively in the author and free of any third party rights, and that any necessary written permissions to quote from other sources have been obtained by the author(s).
3. User Rights
JFU's spirit is to disseminate articles published are as free as possible. Under the Creative Commons license, JFU permits users to copy, distribute, display, and perform the work for non-commercial purposes only. Users will also need to attribute authors and JFU on distributing works in the journal.
4. Rights of Authors
Authors retain the following rights:
- Copyright, and other proprietary rights relating to the article, such as patent rights,
- The right to use the substance of the article in future own works, including lectures and books,
- The right to reproduce the article for own purposes, provided the copies are not offered for sale,
- The right to self-archive the article.
5. Co-Authorship
If the article was jointly prepared by other authors, the signatory of this form warrants that he/she has been authorized by all co-authors to sign this agreement on their behalf, and agrees to inform his/her co-authors of the terms of this agreement.
6. Termination
This agreement can be terminated by the author or JFU upon two months notice where the other party has materially breached this agreement and failed to remedy such breach within a month of being given the terminating partys notice requesting such breach to be remedied. No breach or violation of this agreement will cause this agreement or any license granted in it to terminate automatically or affect the definition of JFU.
7. Royalties
This agreement entitles the author to no royalties or other fees. To such extent as legally permissible, the author waives his or her right to collect royalties relative to the article in respect of any use of the article by JFU or its sublicensee.
8. Miscellaneous
JFU will publish the article (or have it published) in the journal if the articles editorial process is successfully completed and JFU or its sublicensee has become obligated to have the article published. JFU may conform the article to a style of punctuation, spelling, capitalization, referencing and usage that it deems appropriate. The author acknowledges that the article may be published so that it will be publicly accessible and such access will be free of charge for the readers.