Sintesis dan Karakterisasi Sifat Magnet Nanokomposit Fe3O4@PEG:ZnO
DOI:
https://doi.org/10.25077/jfu.11.1.57-61.2022Keywords:
Fe3O4, PEG, ZnO, Presipitasi, Sifat magnetAbstract
Telah dilakukan sintesis dan karakterisasi nanokomposit Fe3O4@PEG:ZnO yang bertujuan untuk mengetahui sifat magnetik dan struktur core-shell dari sampel. Nanokomposit Fe3O4@PEG:ZnO disintesis menggunakan metode presipitasi dengan variasi sampel Fe3O4 dan ZnO yang digunakan yaitu Fe3O4, Fe3O4@ZnO (1:1), Fe3O4@ZnO (1:2), Fe3O4@PEG:ZnO (1:2), dan Fe3O4@PEG:ZnO (1:3). Karakterisasi sampel dilakukan menggunakan X-Ray Diffraction (XRD), Transmission Electron Microscope (TEM), Fourier Transform Infra Red (FTIR), Particle Size Analyzer (PSA), dan Bartington MS2 Magnetic Susceptibility Meter. Pola difraksi sinar-X menunjukkan bahwa sampel tersusun dari fasa Fe3O4 dan fasa ZnO dan ukuran kristal beturut-turut yaitu 17,495 nm; 16,271 nm; 25,449 nm; dan 24,443 nm. Hasil TEM menunjukkan terbentuknya struktur core-shell dimana PEG:ZnO sebagai shell dan Fe3O4 sebagai core. Dari hasil FTIR terdapat ikatan C-O dan C-C yang menunjukkan terbentuknya PEG, ikatan Fe-O menunjukkan terbentuknya Fe3O4,dan ikatan Zn-O menunjukkan terbentuknya ZnO. Pengujian dengan PSA didapatkan ukuran partikel sebesar 33 nm, 23 nm, dan 16 nm dengan distribusi ukuran partikel yaitu 25%, 50%, dan 75%. Pengujian menggunakan Bartington MS2 didapatkan nilai suseptibilitas magnet berturut-turut yaitu (12,34; 11,36; 11; 10,99) x 10-6m3kg-1 dan persentase bulir superparamagnetik berkisar antara 10% sampai 75%.
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