Karakterisasi Keramik (Mg0,8Zn0,2)TiO3+4wt% Bi2O3 sebagai Material Dielectric Resonator Oscillator, Struktur, Mikrostruktur dan Densitasnya
DOI:
https://doi.org/10.25077/jfu.10.2.239-247.2021Abstract
Penelitian ini bertujuan untuk mengkaji potensi aplikasi keramik (Mg0,8Zn0,2)TiO3+4wt% Bi2O3 (disingkat MZT02+4wt%Bi2O3) sebagai resonator pada rangkaian dielectric resonator oscillator (DRO) yang bekerja pada daerah frekuensi gelombang mikro, serta menguji struktur, mikrostruktur dan densitas bulk keramik. Fabrikasi keramik dilakukan dengan ball-milling antara serbuk kristalin MZT02 dengan 4wt% serbuk Bi2O3 pada kecepatan 500 rpm selama 5 jam. Serbuk hasil milling dikompaksi dengan hydraulic-hand press dan cylindrical die press untuk menghasilkan pelet. Semua pelet disinter pada suhu 1100°C selama 4, 6 dan 8 jam untuk menjadi keramik. Struktur keramik dengan waktu penahanan 4 dan 6 jam mengandung fasa MgTiO3=(97,87±8,24) %molar, sisanya fasa TiO2 rutil. Keramik dengan penahanan 8 jam mengandung fasa MgTiO3=(98,44±2,07) %molar, MgTi2O5=(1,49±0,30) %molar dan sisanya TiO2 rutil. Bertambahnya waktu tahan sinter relatif tidak menyebabkan perubahan ukuran parameter kisi, volume sel satuan sedikit berkurang dan densitas bulk juga berkurang dari 2,792, 2,776 menjadi 2,745 g/cm3. Mikrostruktur ketiga keramik berupa gumpalan butir dengan ukuran rata-rata 0,3-1,2 μm disertai pori-pori. Karakterisasi DRO merekam frekuensi resonansi pada posisi yang sama untuk ketiga keramik, yaitu 5,12 GHz memberi bukti bahwa keramik uji dapat diaplikasikan sebagai resonator DRO pada frekuensi gelombang mikro dan variasi waktu tahan sinter tidak merubah performa tersebut.
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This study aims to examine the potential application of (Mg0.8Zn0.2)TiO3+ 4wt% Bi2O3 (abbreviated: MZT02+4wt% Bi2O3) ceramics as a resonator in a dielectric resonator oscillator (DRO) circuit operating in microwave frequencies and to examine its structure, microstructure and bulk density. Ceramic fabrication was carried out by ball-milling between MZT02 crystalline powder and 4wt% Bi2O3 powder at 500 rpm for 5 h. The milled powder was compacted using a hydraulic-hand press and a cylindrical die press to produce pellets. All pellets were sintered at 1100°C for 4, 6 and 8 h to become ceramics. The ceramic structure with 4 and 6 h holding time contains MgTiO3 phase = (97.87 ± 8.24)% molar, the rest was TiO2 rutile phase. Ceramic with 8 h contained MgTiO3phase = (98.44 ± 2.07)% molar, MgTi2O5 = (1.49 ± 0.30) molar% and the remaining TiO2 rutile. Increasing the sinter holding time relatively did not change in the lattice parameter sizes, the unit cell volume was slightly reduced and the bulk density was also reduced from 2.792, 2.776 to 2.745 g/cm3. Microstructure of the three ceramics contain groups of grains with an average size of 0.3-1.2 μm along with pores. DRO characterization recorded the resonant frequency at the same position for the three ceramics, namely 5.12 GHz, providing evidence that the ceramics can be applied as a DRO resonator at microwave frequencies and the variation in sinter holding time did not change this performance
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