Sintesis Lapisan Antikorosi Menggunakan Tanin dari Kulit Batang Bakau sebagai Inhibitor
DOI:
https://doi.org/10.25077/jfu.9.2.277-283.2020Abstract
Telah disintesis lapisan antikorosi menggunakan tanin dari kulit batang bakau sebagai inhibitor. Lapisan dibuat dari campuran tembaga (II) sulfat 1 M, asam borat 0,24 M dan akuabides tanpa dan dengan ekstrak kulit batang bakau pada konsentrasi 0%; 0,5%; 1%; 1,5%; 2%; 2,5% dan 3% volume dengan metode elektrodeposisi. Larutan NaOH 1 M digunakan sebagai media pengkorosi selama 4,5 jam. Karakterisasi morfologi dilakukan pada sampel terbaik dengan X-Ray Difractometer (XRD) setelah elektrodeposisi dengan 2,5% volume inhibitor baik sebelum maupun setelah dilakukan pengukuran laju korosi. Perubahan tegangan setelah elektrodeposisi adalah sebesar 0,1 V untuk semua variasi inhibitor. Laju korosi dan efisiensi inhibisi memiliki perubahan signifikan pada 2,5% volume inhibitor. Karakterisasi dengan mikroskop digital memiliki hasil optimum pada pelat baja dengan 2% inhibitor.
Â
Anticorrosion layers have been synthesized using tannins from mangrove bark as inhibitors. The coating was made from a mixture of 1 M copper (II) sulfate, 0.24 M boric acid and aquabides without and with mangrove bark extract at a concentration of 0%; 0.5%; 1%; 1.5%; 2%; 2.5% and 3% volume by electrodeposition method. 1 M NaOH solution was used as a corroding medium for 4.5 hours. Morphological characterization was performed on the best samples with X-Ray Difractometer (XRD) after electrodeposition with 2.5% volume inhibitors both before and after corrosion rate measurements. The change in voltage after electrodeposition is 0.1 V for all variations of the inhibitor. Corrosion rate and inhibition efficiency have a significant change in 2.5% volume inhibitors. Characterization with a digital microscope has optimum results on steel plates with 2% inhibitors.
References
Dahlan, D., “Electrodeposition of Cu2O Particles by Using Electrolyte Solution Containing Glucopone as Surfactantâ€, Jurnal Ilmiah Fisika 1(2), 18-20 (2009).
Food and Agriculture Organization of the United Nations, The World’s Mangroves 1980-2005 (Food and Agriculture Organization of the United Nations, Roma, 2007), hal 24-25.
Gambier, F., Shah, A.M., Hussin, M.H., Ibrahim, M.N.M., Rahim, A.A., Brosse, N., “Condensed Tannins from Mangrove and Grape Pomace as Renewable Corrosion Inhibitors and Wood Adhesiveâ€, Journal of Advanced Chemical Engineering 8(1), 1-8 (2018).
Haryono, G., Sugiarto, B., Farid, H., Tanoto, Y., 2010, “Ekstrak Bahan Alam sebagai Inhibitor Korosiâ€, Prosiding Seminar Nasional Teknik Kimia “Kejuanganâ€, Yogyakarta, 2016.
Loto, C.A., “Inhibition Effect of Tea (Camellia Sinensis) Extract on the Corrosion of Mild Steel in Dilute Sulphuric Acidâ€, Journal of Materials and Environmental Science 2(4), 335-344 (2011).
Mahaputri, S.A., Dahlan, D., Yetri, Y., “The Use of Cacao Peels Extract (Theobrema Cacao) as the Corrosion Inhibitor on Steel Layers Electrodepositionâ€, Petrochemical Science 5(3), 1-5 (2018).
Obot, I.B., Umoren, S.A., Obi-Egbedi, N.O., “Corrosion Inhibition and Adsorption Behaviour for Aluminuim by extract of Aningeria robusta in HCL solution: Synergistic Effect of Iodide Ions, Journal of Materials and Environmental Science 2(1), 60-71 (2011).
Tissos, N.P., Dahlan, D., Yetri, Y., “Synthesis of Cuprum (Cu) Layer by Electrodeposition Method with Theobrema Cacao Peels as Corrosion Protector of Steelâ€, Advance Science Engineering Information Technology 8(4), 1290-1295 (2018).
Yetri, Y., “Inhibisi Korosi dan Pemulihan Sifat Mekanik Baja Lunak Menggunakan Ekstrak Kulit Buah Kakao (Theobroma cacao) dalam Media Asamâ€, Disertasi S3, Universitas Andalas, 2015.
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2020 Muhammad Frassetia Lubis, Dahyunir Dahlan
This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.
Please find the rights and licenses in JFU (Jurnal Fisika Unand).
1. License
The non-commercial use of the article will be governed by the Creative Commons Attribution license as currently displayed on Creative Commons Attribution-NonCommercial 4.0 International License.
2. Authors Warranties
The author warrants that the article is original, written by stated author(s), has not been published before, contains no unlawful statements, does not infringe the rights of others, is subject to copyright that is vested exclusively in the author and free of any third party rights, and that any necessary written permissions to quote from other sources have been obtained by the author(s).
3. User Rights
JFU's spirit is to disseminate articles published are as free as possible. Under the Creative Commons license, JFU permits users to copy, distribute, display, and perform the work for non-commercial purposes only. Users will also need to attribute authors and JFU on distributing works in the journal.
4. Rights of Authors
Authors retain the following rights:
- Copyright, and other proprietary rights relating to the article, such as patent rights,
- The right to use the substance of the article in future own works, including lectures and books,
- The right to reproduce the article for own purposes, provided the copies are not offered for sale,
- The right to self-archive the article.
5. Co-Authorship
If the article was jointly prepared by other authors, the signatory of this form warrants that he/she has been authorized by all co-authors to sign this agreement on their behalf, and agrees to inform his/her co-authors of the terms of this agreement.
6. Termination
This agreement can be terminated by the author or JFU upon two months notice where the other party has materially breached this agreement and failed to remedy such breach within a month of being given the terminating partys notice requesting such breach to be remedied. No breach or violation of this agreement will cause this agreement or any license granted in it to terminate automatically or affect the definition of JFU.
7. Royalties
This agreement entitles the author to no royalties or other fees. To such extent as legally permissible, the author waives his or her right to collect royalties relative to the article in respect of any use of the article by JFU or its sublicensee.
8. Miscellaneous
JFU will publish the article (or have it published) in the journal if the articles editorial process is successfully completed and JFU or its sublicensee has become obligated to have the article published. JFU may conform the article to a style of punctuation, spelling, capitalization, referencing and usage that it deems appropriate. The author acknowledges that the article may be published so that it will be publicly accessible and such access will be free of charge for the readers.
