PENGARUH PENAMBAHAN BAHAN DOPAN TA2O5 PADA BAHAN PIEZOELEKTRIK RAMAH LINGKUNGAN (K0,5NA0,5)0,96LI0,04NO3 DENGAN MENGGUNAKAN SINTESIS METODE MOLTEN SALT

Authors

  • Awaluddin - Jurusan Fisika FMIPA Universitas Andalas Kampus Unand, Limau Manis, Padang, 25163
  • Alimin Mahyudin Jurusan Fisika FMIPA Universitas Andalas Kampus Unand, Limau Manis, Padang, 25163
  • Syahfandi Ahda Badan Tenaga Nuklir Nasional

DOI:

https://doi.org/10.25077/jfu.4.2.%25p.2015

Abstract

ABSTRAK

Telah dilakukan penelitian tentang pengaruh penambahan bahan dopan Ta2O5 pada bahan piezoelektrik ramah lingkungan (K0,5Na0,5)0,96Li0,04NbO3(KNLN)dengan metode sintesis  molten salt.  Dalam penelitian ini  dilakukan variasi persentase mol bahan dopan Ta2O5  sebesar 3%, 7%, 10% dan 12%. Sintesis dilakukan dengan parameter penggerusan selama 4 jam, kalsinasi pada suhu 2500C selama 1 jam, dan sintering pada suhu 9200C selama 4 jam. Berdasarkan analisis XRD dapat diidentifikasi bahwa struktur bahan piezoelektrik KNLNT (KNLN + dopan) pada penambahan 3% dan 7% cenderung ortorhombik, sedangkan pada penambahan 10% dan 12% cenderung tetragonal. Pada penambahan 7% mol Ta2O5 terjadinya penurunan nilai c/a yang tajam. Hal ini menunjukkan bahwa pada rentang komposisi inilah daerah motphotropic phase boundary berada.  Hasil SEM menunjukkan pada penambahan dopan 3% ukuran partikel adalah 0,0884-0,7869 μm dan penambahan dopan 12% terjadi lonjakan tajam ukuran partikel yaitu sebesar 0,1563-1,5793 μm.

Abstract

Research on the effect of the addition of dopant materials Ta2O5 on environmentally friendly piezoelectric materials (K0,5Na0,5)0,96Li0,04NbO3(KNLN) with molten salt synthesis method has been conducted. In this study, the mole percentage dopant materials varied by 3%, 7%, 10% and 12%. Synthesis was conducted with parameters: grinding for 4 hours, temperature calcination at 2500Cfor 1 hour, and sintering at a temperature of 9200C for 4 hours. Based on XRD analysis, it can be identified that the structure of the piezoelectric material KNLNT (KNLN + dopant) on the addition of 3% and 7% tend orthorhombic, while the addition of 10% and 12% tend to tetragonal. In addition of 7 % mol of Ta2O5, the c/a value decrese sharply. This value indicates that motphotropic phase boundary is located in this composition range. The SEM results show that at addition of 3% dopants the particle size is from 0.0884 to 0.7869 μm and at addition of 12% dopant the particle size increase sharply that  to 0.15623 until 1.5793 μm. 

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Published

2024-10-26

How to Cite

-, A., Mahyudin, A., & Ahda, S. (2024). PENGARUH PENAMBAHAN BAHAN DOPAN TA2O5 PADA BAHAN PIEZOELEKTRIK RAMAH LINGKUNGAN (K0,5NA0,5)0,96LI0,04NO3 DENGAN MENGGUNAKAN SINTESIS METODE MOLTEN SALT. Jurnal Fisika Unand, 4(2). https://doi.org/10.25077/jfu.4.2.%p.2015

Issue

Vol. 4 No. 2: April 2015

Section

Articles

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Copyright (c) 2024 Awaluddin -, Alimin Mahyudin, Syahfandi Ahda

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